Hanna Instruments

The HI-4114 is a Potassium Combination ISE ideal for the determination of Potassium ions in wine, waters, soils and biological samples.

The HI-4114 potassium ion selective electrode is a complete potentiometric cell that contains a silver/silver chloride (Ag/AgCl) reference housed within a PEI plastic body with a sodium chloride electrolyte. The internal elements are isolated from the sample by an organic polymer sensing membrane.

Hanna’s liquid membrane combination ISEs are designed with a cone style junction. The skirted cone geometry of the sensor forms the liquid junction with the test solution at the tip of the junction cone, producing a highly stable reference potential and consistent flow rates of electrolyte into the solution. A simple press of the top portion of the ISE makes it easy to empty the electrolyte fill solution and replace when necessary.

For the HI-4114 to measure potassium accurately, it is important that the ionic strength of the standards and sample be adjusted to a high and constant value with the potassium ionic strength adjuster (ISA) solution. The ISA ensures that the activity coefficient is constant so the concentration of free potassium ions can be measured. Measuring all solutions with a constant ionic strength reduces the margin of error between measurements. The HI-4114 potassium liquid membrane ISE can measure from 1µM (0.039 mg/L) to 1M (39,100 mg/L).